The unoccupied electronic structure characterization of hydrothermally grown ThO<sub>2</sub> single crystals

نویسندگان

  • Peter Dowben
  • T D. Kelly
  • J C. Petrosky
  • J W. McClory
  • J M. Mann
  • J W. Kolis
  • Xin Zhang
  • P. A. Dowben
  • T. D. Kelly
  • J. W. McClory
  • J. M. Mann
  • J. W. Kolis
چکیده

The unoccupied electronic structure characterization of hydrothermally grown ThO 2 single crystals" (2014). Peter Dowben Publications. Paper 265. 1 Introduction It is often stated that Th has no 5f electrons and instead adopts the electronic configuration [Rn]6d 2 7s 2. This is an extension of the idea that there are no occupied Th valence states when Th is a cation Th 4+ in a compound such as ThO 2. In this scheme, the valence maximum is dominated by O 2p character, as a result of the transfer of the outer Th 6d

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تاریخ انتشار 2015